Coal tar. María Antonia Diez, Roberto Garcia, in New Trends in Coal Conversion, 2019. Concluding remarks. With coal tar as a byproduct from cokemaking, coal tar availability will continue to depend on the consumption of coke in the blast furnace for iron and steel production. Thus, the conditions of coke production in recovery coke ovens will play a decisive role in determining ...
But because that its relative density is higher than and asphaltene content is close to 50% [6] (mass fraction), hightemperature coal tar is not suitable for the production of aerospace fuel. Medium and low temperature coal tar is a liquid product with high condensation degree obtained by pyrolysis of lowrank coal at 600 to 800°C.
The tar production rate is kg/s and is analyzed to contain 85% carbon and 15% hydrogen by weight. The heating value of the tar is 42,000 kJ/kg. The oxygen is produced from air using an oxygenseparation unit that consumes 4000 kJ of energy/kg of the oxygen produced (assume full conversion of char).
naphthalene oil of coal tar [3538]. Therefore, further explorat ions on the use of catalysts to promote LRC pyrolysis staged utilization to produce naphthalene oilrich
Odour: Peculiar, naphthalenelike (Singh, Goyal and Kaur, 2015) ... PROCESS DESCRIPTION Coal Tar ... 2019. Coal Tar Production Processes and Potential of PAHs Release into the Environment. [online ...
This report proffers the detailed cost evaluation of the production of naphthalene from coal tar. In this process, the coal tar is subjected to the distillation and fractionation process. Further, the middle fractions, which contain most of the naphthalene, are cooled and crystalized to yield crude naphthalene. Lastly, the crude naphthalene is ...
At the moment, most of the aluminum smelters utilize coal tar pitch as binder in their prebaked carbon anode (and graphitized carbon cathode) production processes. Hence, the prediction of the thermodynamic properties of PAHs present in coal tar pitch aimed at phase behavior description of coal tar pitch during heat treatment will be the main ...
Coal tar is a byproduct of metallurgical coke or oil coke production. There are many works devoted to an increased yield and improved quality of needle coke [15]. Coal tar has a complex composition with a high level of valuable aromatic compounds, like phenol, naphthalene, anthracene, etc. [6].Due to its content, coal tar can be used as a rich
1. Introduction. With the development of coal utilization technologies such as gasification, liquefaction, carbonization, and coking, a large number of coal tar or coal tar byproducts have been produced, among which carbonization and liquefaction are the processes with coal tar as the main product. 1,2 Although medium and lowtemperature coal tars have higher contents of aliphatic ...
Coal Tar. L. Roberts, in Encyclopedia of Toxicology (Third Edition), 2014 Background (Significance/History) Coal tar is a complex hydrocarbon mixture produced by thermal destruction (pyrolysis) of coal, typically a dark viscous liquid or semisolid with a smoky or naphthenic odor. The composition of coal tar will be influenced by the process used for pyrolytic distillation as well as by the ...
Coal tar naphthalene oil fraction (CTNOF) is typically obtained as a byproduct of the coking process in steel production. When coal is subjected to high temperatures in the absence of air (coking), it undergoes thermal decomposition, yielding various byproducts including coal tar [].This tar can be further processed to extract different fractions, one of which is naphthalene oil [2, 3].
Naphthalene Production from coal tar; The distillation and fractionation techniques are used in this process. Crude naphthalene is produced by cooling and crystallizing the middle portions, which contain the majority of the naphthalene. In order to produce refined naphthalene, the crude product is then placed into a distillation, washing, and ...
Coal tar ( ) and coal tar pitch ( ) are the byproducts of the hightemperature treatment of coal to make coke or natural gas. These chemical products usually are thick, black or dark brown liquids or semisolids with a naphthalenelike odor. Coal tar also has a sharp, burning taste.
Introduction. The carbonization of coal to produce metallurgical coke in slottype recovery ovens is the main source of coal tar production, with this coal conversion process constituting the second largest application of coal. Coal tar production is not a primary process target: the main target in the process is the production of metallurgical ...
The Process Intensification for Syngas Hydrogen key technology area addresses control of chemical reactions in increasingly modular and intrinsically efficient reactors, allowing for streamlined processes with wellcoordinated unit operations, and with a focus on gasification of biomass and carbonaceous wastes into syngas, s.
The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic threecolumn system is Gcal/t of commercial naphthalene (of purity wt %). If heat is recycled in the threecolumn system, the energy consumption is ...
Coal tar, a black, sticky liquid thicker than water, is produced when coal is heated in the absence of air, a process called destructive distillation. Much coal tar is produced by the steel industry as it produces millions of tons of coke each year to fuel the furnaces used in separating iron from its ores.
Naphthalene is an important component of high temperature coal tar and its content can reach more than 10%. Catalytic polycondensation of naphthalene is an effective way to prepare mesophase pitch and functional carbon materials. ... which may provide valuable hints for exploring the production process of mesophase naphthalene pitch. Declare of ...
Most naphthalene is derived from coal tar. From the 1960s until the 1990s, significant amounts of naphthalene were also produced from heavy petroleum fractions during petroleum refining, but presentday production is mainly from coal tar. Approximately tons are produced annually. Naphthalene is the most abundant single component of coal tar.
Naphthalene was first isolated from coal tar in 1819 by Alexander Garden; it represents about 10% of this complex mixture of aromatics. The industrial importance of naphthalene dates from the latter half of the last century, owing mainly to the ease with which it can be converted into sulfonic acids and thence also to the naphthols, for use as dyestuffs intermediates.
To trace the behavior of naphthalene in the pyrolysis of coal tar, the pyrolysis of coal tar containing 14Clabeled naphthalene was carried out at 800−950 °C for 40−50 s. It was found that naphthalene has significant pyrolysis reactivity. The distributions of the radioactivities in compounds with 3−5 rings were,, and % at 800, 900, and 950 °C for 50 s, respectively ...
To develop the in situ underground pyrolysis process of tarrich coal more scientifically, the effect of temperature and pressure on the distribution of pyrolysis products should be clarified. This paper selected the typical components in five distillates of light tar, phenol tar, naphthalene tar, washing tar, and anthracene tar as the main reaction products. 32 typical secondary reactions ...
In a process for obtaining substantially sulfur free pure naphthalene from bituminous coal tar and thionaphthene as a byproduct, a dephenolized thionaphthenecontaining naphthalene fraction from oxidative purification is extracted with concentrated sulfuric acid and acetic acid anhydride in benzene.
sumer products. Coal tars are used primarily for the production of refined chemicals and coaltar products, such as creosote, coaltar pitch, and crude naphthalene and anthracene oils from the distillation of crude coal tar. Coal tar has been used as a fuel in openhearth furnaces and blast furnaces in the steel industry, as a binder and filler in
The organic chemistry industry is based on organic compounds derived from coal, petroleum and gas. Coal tars derived from the carbonisation process are complex mixtures, of which the polycyclic aromatic hydrocarbons (PAH's) are the main component. One of the most important PAH's is naphthalene, which represents between 10 to 12% of the recent years, new applications for industrial ...
Report No. COAL TAR CHEMICALS JAMES J. L. MA December 1976 A private report by the a PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA
The naphthalene samples studied in this work were produced by the chemical industry. Fig. 1 shows a process for the production of naphthalene with different degrees of purity. The refined naphthalene came from the catalytic hydrogenation process, (NAFR) (% purity); the industrial naphthalene from a series of distillations (NAFD) (% purity) and the crystallised naphthalene (NAFC) (99 ...
Coal tar is a thick dark liquid which is a byproduct of the production of coke and coal gas from coal. It is a type of has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis (dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and ...
Coal tar is a hazardous and toxic waste, a byproduct of coal gasification processes. Coal tar is a waste produced in industrial fields such as steel, power plant, and the cement industry. As a ...
Naphthalene is the simplest polycyclic aromatic hydrocarbon, and can be used as a precursor to many other complex aromatics. Current industrial processes remove it from coal tar or petroleum during the refining and distillation steps. The process reported here is much greener, albeit on a much smaller scale.
% of the naphthalene in the coal tar; % of the naphthalene fraction is lost with the press runoff. 3. The market is limited because of the minimum product range: only liquid naphthalene can be shipped to the customer. (In April 2012, Rostekhnadzor banned the shipment of pressed naphthalene in railroad cars for lack of mechanization.
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