the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
Petroleum gas production. For producing petroleum gas, the optimal advanced oil processing ratio is 20:5:17 (advanced oil processing : heavy oil cracking : light oil cracking), and 8:2:7 is close enough. Using coal liquefaction, the ratio is 60:39:55 (coal liquefaction : heavy oil cracking : light oil cracking), and 12:8:11 is close enough.
The article contains sections titled: 1. Introduction Commercial Development Historical Background 2. Indirect Coal Liquefaction Preparation of Synthesis Gas Co...
Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA ...
The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
Gasification While the goal of combustion is to produce the maximum amount of heat possible by oxidizing all the combustible material, the goal of gasification is to convert most of the combustible solids into combustible gases such as carbon monoxide, hydrogen, and methane. Gasification reactions
Coal liquefaction is a process in which coal is converted into liquid fuels or petrochemicals. There are several processes used to accomplish this task, the two most common being the "indirect route" and the "direct route". [1]
The principal direct liquefaction processes are: 1. Extraction. Some bioderived and waste materials yield an oil product by extraction that can directly be used as feed material for refining.
An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogenrich gases at ...
The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significance for improving the oil yield of the direct liquefaction process and reducing the amount of pollution emitted from this oilcontaining organic solid waste. In ...
Description Direct coal liquefaction involves contacting coal directly with a catalyst at elevated temperatures and pressures with added hydrogen (H 2 ), in the presence of a solvent to form a raw liquid product which is further refined into product liquid fuels.
Through a onestage liquefaction method using a powdered iron catalyst and hydrogen donor solvent, the NEDOL process can attain a high liquefied oil yield from a wide range of coal ranks under a mild reaction condition. Through these technical characteristics, the NEDOL process has the following advantages in commercialization.
Coal resources have been used to produce liquid transportation fuels by several process routes, collectively referred to as coal liquefaction or, more generally stated, as Coal to Liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
When considering the development of coal liquefaction process using syngas, in addition to the above typical processes, hydrothermal liquefaction process is a technology worthy of reference. Hydrothermal liquefaction [110], [111], [112] is an effective and emerging technology that can convert both coals and biomass containing high moisture ...
Coal Liquefaction It is an alternative route to produce diesel and gasoline and makes economic sense only in a world of high crude oil prices,Also called Coal to Liquid (CTL) technology. The process involves gasification of coal, which in turn will produce synthetic gas (a mix of CO+H2).
Other articles where SASOL process is discussed: coal utilization: The FischerTropsch process: .1950s in South Africa (the SASOL process) and now supplies as much as onethird of that country's liquid fuels. ... coal liquefaction process. Learn about this topic in these articles: coal processing. In coal utilization: The FischerTropsch ...
misc{etde_609560, title = {Effect of catalyst addition on coliquefaction process of coal and biomass in supercritical water; Chorinkaisui wo mochiita sekitan biomass doji ekika process ni okeru shokubai tenka koka} author = {Yokura, H, Nonaka, H, Matsumura, Y, Tsutsumi, A, and Yoshida, K} abstractNote = {Mixture of coal and cellulose was liquefied in supercritical water (400degC, 25 MPa ...
Fig. 12 shows the total costs of the whole coal liquefaction process together with the costs of four major parts: coal price, (coal) transportation, DCL production and distribution. Among three, "DCL_R" is the most economical one, the price of which is only two third of "DCL_H". For "DCL_H" and "DCL_R", the price caused by the ...
Carlson, F B, Yardumian, L H, Atwood, M T. TOSCOAL process: coal liquefaction and char production. Paper No. 15e. [Application of oil shale retorting technology to coal processing; process description]. United States.
A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone ...
An improved coal liquefaction process is provided which enables conversion of a coaloil slurry to a synthetic crude refinable to produce larger yields of gasoline and diesel oil. The process is characterized by a twostep operation applied to the slurry prior to catalytic desulfurization and hydrogenation in which the slurry undergoes partial ...
Highlights. Coal liquefaction, the conversion of coal to a cleanburning, lowsulfurcontent fuel, is a technology that can augment petroleumderived products such as gasoline and boiler fuels and help meet the requirement for large supplies of liquid fuel. Direct liquefaction produces liquids through the interaction of coal and hydrogen at ...
Coal liquefaction process employing fuel from a combined gasifier. Patent Schmid, B. Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to ...
The byproduct from this hydrocracking process of coal liquefaction is defined as the precursor through the further processing to make super hard asphalt (SHA) as shown in Fig. 1. SHA is a dark colored solid at ambient temperature, which normally is about 30% of the total coal used as the feedstock ( Wu and Xie, 2010 ).
The work described is primarily concerned with the application of coal cleaning methods and solids separation methods to the Catalytic TwoStage Liquefaction (CTSL) Process. Additionally a predispersed catalyst was evaluated in a thermal/catalytic configuration, and an alternative nickel molybdenum catalyst was evaluated for the CTSL process.
In principle, the process of coal liquefaction involves chemical compounds which also occur in other carbochemical or petrochemical processes. It is well known that a number of these substances may be carcinogenic, teratogenic or mutagenic. The concentration of benzo(a)pyrene in coal liquefaction products can be between 50 and 60 μg g −1.
4. Coal Liquefaction Coal liquefaction is the conversion of coal into a synthetic oil in order to supplement natural sources of petroleum. It is an attractive technology because 1) It is well developed and thus could be implemented fairly rapidly and 2) There are relatively large quantities of coal reserves. 5.
A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to ...
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