Steam Community :: Guide :: PSO2 NA Episode 6: Speeding to endgame ...
The 4th recommended quest has a 200% XP boost and is your best way to grind xp outside of keys. It rotates daily between 5 different quests. A Broken World of Twisted Shadows, The Menacing Castle, and Disturbing Whistle of Chaos (Piper) are all excellent for grinding, the other two not so much.